Exploration of 1,2-phenylenediboronic esters as potential bidentate catalysts for organic synthesis - Research portal of Justus Liebig University Giessen:

Journal article

Exploration of 1,2-phenylenediboronic esters as potential bidentate catalysts for organic synthesis

Authors list: Bader, SL; Kessler, SN; Zampese, JA; Wegner, HA

Publication year: 2013

Pages: 531-537

Journal: Monatshefte für Chemie - Chemical Monthly

Volume number: 144

Issue number: 4

ISSN: 0026-9247

DOI Link: https://doi.org/10.1007/s00706-012-0898-y

Publisher: Springer

Abstract:
Recently, we described the first inverse electron demand Diels-Alder reaction of 1,2-diazene catalyzed by a bidentate Lewis acid. Herein we investigate 1,2-phenylenediboronic esters as potential catalysts for this transformation offering higher stability and easier handling than the currently used boranthracene derivatives. Different 1,2-phenylenediboronic esters were prepared and their ability to form bidentate coordination complexes with phthalazine was analyzed. Although a 1:1 complex was observed, X-ray analysis revealed binding only in a monodentate fashion.

Authors/Editors

- Uni.-Prof. Dr. Hermann Andreas Wegner

Citation Styles

Harvard Citation style: Bader, S., Kessler, S., Zampese, J. and Wegner, H. (2013) Exploration of 1,2-phenylenediboronic esters as potential bidentate catalysts for organic synthesis, Monatshefte für Chemie - Chemical Monthly, 144(4), pp. 531-537. https://doi.org/10.1007/s00706-012-0898-y

APA Citation style: Bader, S., Kessler, S., Zampese, J., & Wegner, H. (2013). Exploration of 1,2-phenylenediboronic esters as potential bidentate catalysts for organic synthesis. Monatshefte für Chemie - Chemical Monthly. 144(4), 531-537. https://doi.org/10.1007/s00706-012-0898-y