Journal article

Non-oxidic nanoscale composites : single-crystalline titanium carbide nanocubes in hierarchical porous carbon monoliths


Authors listSonnenburg, K; Smarsly, BM; Brezesinski, T

Publication year2009

Pages3300-3304

JournalPhysical Chemistry Chemical Physics

Volume number11

Issue number17

ISSN1463-9076

DOI Linkhttps://doi.org/10.1039/b822437d

PublisherRoyal Society of Chemistry


Abstract
We report the preparation of nanoscale carbon-titanium carbide composites with carbide contents of up to 80 wt%. The synthesis yields single-crystalline TiC nanocubes 20-30 nm in diameter embedded in a hierarchical porous carbon matrix. These composites were generated in the form of cylindrical monoliths but can be produced in various shapes using modern sol-gel and nanocasting methods in conjunction with carbothermal reduction. The monolithic material is characterized by a combination of microscopy, diffraction and physisorption. Overall, the results presented in this work represent a concrete design template for the synthesis of non-oxidic nanoscale composites with high surface areas.



Citation Styles

Harvard Citation styleSonnenburg, K., Smarsly, B. and Brezesinski, T. (2009) Non-oxidic nanoscale composites : single-crystalline titanium carbide nanocubes in hierarchical porous carbon monoliths, Physical Chemistry Chemical Physics, 11(17), pp. 3300-3304. https://doi.org/10.1039/b822437d

APA Citation styleSonnenburg, K., Smarsly, B., & Brezesinski, T. (2009). Non-oxidic nanoscale composites : single-crystalline titanium carbide nanocubes in hierarchical porous carbon monoliths. Physical Chemistry Chemical Physics. 11(17), 3300-3304. https://doi.org/10.1039/b822437d


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