Journalartikel

Jahr der Veröffentlichung: 2004

Seiten: 344-348

Zeitschrift: European Journal of Inorganic Chemistry

Bandnummer: 2004

Heftnummer: 2

ISSN: 1434-1948

DOI Link: https://doi.org/10.1002/ejic.200300456

Verlag: Wiley-VCH Verlag

Abstract: 
A novel structural motif in oxalate bridged copper(II) complexes has been prepared namely a metallamacrocyclic compound of the dinucleating ligand 1,3-bis[bis(2-pyridylmethyl)amino]benzene (= 1,3-tpbd). It could be demonstrated that the magnetic properties of copper(II) complexes of the 1,3-tpbd ligand can be adjusted from weakly ferromagnetic (J = +9.3 cm(-1)) to strongly antiferromagnetic [J = -366(9) cm(-1)] by variation of the additional ligands (e.g. perchlorate, azide, oxalate etc.). (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2004.

Harvard-Zitierstil: Foxon, S., Walter, O., Koch, R., Rupp, H., Müller, P. and Schindler, S. (2004) Tuning the magnetic properties of a dinuclear copper complex: From ferromagnetic to antiferromagnetic coupling, European Journal of Inorganic Chemistry, 2004(2), pp. 344-348. https://doi.org/10.1002/ejic.200300456

APA-Zitierstil: Foxon, S., Walter, O., Koch, R., Rupp, H., Müller, P., & Schindler, S. (2004). Tuning the magnetic properties of a dinuclear copper complex: From ferromagnetic to antiferromagnetic coupling. European Journal of Inorganic Chemistry. 2004(2), 344-348. https://doi.org/10.1002/ejic.200300456