Copper(I) catalysts for the stereoselective addition of N-chloroamines to double bonds: A diastereoselective radical cyclisation - Forschungsportal der Justus-Liebig-Universität Gießen:

Journalartikel

Copper(I) catalysts for the stereoselective addition of N-chloroamines to double bonds: A diastereoselective radical cyclisation

Autorenliste: Heuger, G; Kalsow, S; Göttlich, R

Jahr der Veröffentlichung: 2002

Seiten: 1848-1854

Zeitschrift: European Journal of Organic Chemistry

Bandnummer: 2002

Heftnummer: 11

ISSN: 1434-193X

DOI Link: https://doi.org/10.1002/1099-0690(200206)2002:11<1848::AID-EJOC1848>3.0.CO;2-V

Verlag: Wiley

Abstract:
Copper(I) catalysts for the diastereoselective radical cyclisation of N-chloro-N-pentenylamines have been developed. The stereoselectivity of the cyclisation depends upon the ligands employed, proving that the radical is bound to the catalyst during the formation of the new stereocentre and making a catalyst-influenced stereoselective radical reaction possible, The influence of the catalyst on the Beckwith-Houk transition states is discussed.

Autoren/Herausgeber

- Uni.-Prof. Dr. Richard Göttlich

Zitierstile

Harvard-Zitierstil: Heuger, G., Kalsow, S. and Göttlich, R. (2002) Copper(I) catalysts for the stereoselective addition of N-chloroamines to double bonds: A diastereoselective radical cyclisation, European Journal of Organic Chemistry, 2002(11), pp. 1848-1854. https://doi.org/10.1002/1099-0690(200206)2002:11<1848::AID-EJOC1848>3.0.CO;2-V

APA-Zitierstil: Heuger, G., Kalsow, S., & Göttlich, R. (2002). Copper(I) catalysts for the stereoselective addition of N-chloroamines to double bonds: A diastereoselective radical cyclisation. European Journal of Organic Chemistry. 2002(11), 1848-1854. https://doi.org/10.1002/1099-0690(200206)2002:11<1848::AID-EJOC1848>3.0.CO;2-V