Copper(I) catalysts for the stereoselective addition of N-chloroamines to double bonds: A diastereoselective radical cyclisation - Research portal of Justus Liebig University Giessen:

Journal article

Copper(I) catalysts for the stereoselective addition of N-chloroamines to double bonds: A diastereoselective radical cyclisation

Authors list: Heuger, G; Kalsow, S; Göttlich, R

Publication year: 2002

Pages: 1848-1854

Journal: European Journal of Organic Chemistry

Volume number: 2002

Issue number: 11

ISSN: 1434-193X

DOI Link: https://doi.org/10.1002/1099-0690(200206)2002:11<1848::AID-EJOC1848>3.0.CO;2-V

Publisher: Wiley

Abstract:
Copper(I) catalysts for the diastereoselective radical cyclisation of N-chloro-N-pentenylamines have been developed. The stereoselectivity of the cyclisation depends upon the ligands employed, proving that the radical is bound to the catalyst during the formation of the new stereocentre and making a catalyst-influenced stereoselective radical reaction possible, The influence of the catalyst on the Beckwith-Houk transition states is discussed.

Authors/Editors

- Uni.-Prof. Dr. Richard Göttlich

Citation Styles

Harvard Citation style: Heuger, G., Kalsow, S. and Göttlich, R. (2002) Copper(I) catalysts for the stereoselective addition of N-chloroamines to double bonds: A diastereoselective radical cyclisation, European Journal of Organic Chemistry, 2002(11), pp. 1848-1854. https://doi.org/10.1002/1099-0690(200206)2002:11<1848::AID-EJOC1848>3.0.CO;2-V

APA Citation style: Heuger, G., Kalsow, S., & Göttlich, R. (2002). Copper(I) catalysts for the stereoselective addition of N-chloroamines to double bonds: A diastereoselective radical cyclisation. European Journal of Organic Chemistry. 2002(11), 1848-1854. https://doi.org/10.1002/1099-0690(200206)2002:11<1848::AID-EJOC1848>3.0.CO;2-V