Journalartikel

Jahr der Veröffentlichung: 2015

Seiten: 1226-1234

Zeitschrift: Beilstein Journal of Organic Chemistry

Bandnummer: 11

Open Access Status: Gold

DOI Link: https://doi.org/10.3762/bjoc.11.136

Verlag: Beilstein-Institut

Abstract: 
N-Alkyl-N-chlorosulfonamides add to alkenes under
copper(I) catalysis. In reactions of styrene derivatives with terminal
double bonds the addition products were obtained in excellent yield and
high regioselectivity. Lower yields are obtained in addition reactions
to non-aromatic alkenes. The reaction most likely proceeds via a redox
catalysis and amidyl radicals, a concerted mechanism has been ruled out
and a polar mechanism via chloronium ions would lead to the opposite
regiochemistry.

Harvard-Zitierstil: Heuger, G. and Göttlich, R. (2015) Intermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compounds, Beilstein Journal of Organic Chemistry, 11, pp. 1226-1234. https://doi.org/10.3762/bjoc.11.136

APA-Zitierstil: Heuger, G., & Göttlich, R. (2015). Intermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compounds. Beilstein Journal of Organic Chemistry. 11, 1226-1234. https://doi.org/10.3762/bjoc.11.136