Journal article
Authors list: Heuger, G; Göttlich, R
Publication year: 2015
Pages: 1226-1234
Journal: Beilstein Journal of Organic Chemistry
Volume number: 11
Open access status: Gold
DOI Link: https://doi.org/10.3762/bjoc.11.136
Publisher: Beilstein-Institut
Abstract:
N-Alkyl-N-chlorosulfonamides add to alkenes under
copper(I) catalysis. In reactions of styrene derivatives with terminal
double bonds the addition products were obtained in excellent yield and
high regioselectivity. Lower yields are obtained in addition reactions
to non-aromatic alkenes. The reaction most likely proceeds via a redox
catalysis and amidyl radicals, a concerted mechanism has been ruled out
and a polar mechanism via chloronium ions would lead to the opposite
regiochemistry.
Citation Styles
Harvard Citation style: Heuger, G. and Göttlich, R. (2015) Intermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compounds, Beilstein Journal of Organic Chemistry, 11, pp. 1226-1234. https://doi.org/10.3762/bjoc.11.136
APA Citation style: Heuger, G., & Göttlich, R. (2015). Intermolecular addition reactions of N-alkyl-N-chlorosulfonamides to unsaturated compounds. Beilstein Journal of Organic Chemistry. 11, 1226-1234. https://doi.org/10.3762/bjoc.11.136
