Journalartikel

Jahr der Veröffentlichung: 2013

Seiten: 2202-2208

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 639

Heftnummer: 12-13

ISSN: 0044-2313

eISSN: 1521-3749

DOI Link: https://doi.org/10.1002/zaac.201300277

Verlag: Wiley

Abstract: 
Iodotrimethylplatinum(IV) forms the complexes [PtMe3L2I] [L = 4-dimethylaminopyridine (4-DMAP), 3-bromopyridine (3-BrPy), and 4-cyanopyridine (4-CNPy)] in good yield on treatment with substituted pyridines. The H-1 NMR spectrum of [PtMe3(4-DMAP)(2)I] (1) in CDCl3 shows no dissociation of the monomeric unit, while both the complexes [PtMe3(3-BrPy)(2)I] (2) and [PtMe3(4-CNPy)(2)I] (3) undergo dissociation in CDCl3 to a different extent to form the dimeric complexes [{PtMe3(3-BrPy)I}(2)] and [{PtMe3(4-CNPy)I}(2)], respectively. The crystal structures of 1 and 2 were determined to investigate the binding situation of these mononuclear trimethylplatinum(IV) complexes of pyridines.

Harvard-Zitierstil: Ghosh, B., Hausmann, H., Serafin, M., Lentz, D. and Schlecht, S. (2013) A Comparative Study of the Solution Behavior of Iodotrimethylplatinum(IV) Complexes of Pyridines, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 639(12-13), pp. 2202-2208. https://doi.org/10.1002/zaac.201300277

APA-Zitierstil: Ghosh, B., Hausmann, H., Serafin, M., Lentz, D., & Schlecht, S. (2013). A Comparative Study of the Solution Behavior of Iodotrimethylplatinum(IV) Complexes of Pyridines. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 639(12-13), 2202-2208. https://doi.org/10.1002/zaac.201300277