Journal article
Authors list: Ghosh, Biswa Nath; Hausmann, Heike; Serafin, Michael; Lentz, Dieter; Schlecht, Sabine
Publication year: 2013
Pages: 2202-2208
Journal: Journal of Inorganic and General Chemistry
Volume number: 639
Issue number: 12-13
ISSN: 0044-2313
eISSN: 1521-3749
DOI Link: https://doi.org/10.1002/zaac.201300277
Publisher: Wiley
Abstract:
Iodotrimethylplatinum(IV) forms the complexes [PtMe3L2I] [L = 4-dimethylaminopyridine (4-DMAP), 3-bromopyridine (3-BrPy), and 4-cyanopyridine (4-CNPy)] in good yield on treatment with substituted pyridines. The H-1 NMR spectrum of [PtMe3(4-DMAP)(2)I] (1) in CDCl3 shows no dissociation of the monomeric unit, while both the complexes [PtMe3(3-BrPy)(2)I] (2) and [PtMe3(4-CNPy)(2)I] (3) undergo dissociation in CDCl3 to a different extent to form the dimeric complexes [{PtMe3(3-BrPy)I}(2)] and [{PtMe3(4-CNPy)I}(2)], respectively. The crystal structures of 1 and 2 were determined to investigate the binding situation of these mononuclear trimethylplatinum(IV) complexes of pyridines.
Citation Styles
Harvard Citation style: Ghosh, B., Hausmann, H., Serafin, M., Lentz, D. and Schlecht, S. (2013) A Comparative Study of the Solution Behavior of Iodotrimethylplatinum(IV) Complexes of Pyridines, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 639(12-13), pp. 2202-2208. https://doi.org/10.1002/zaac.201300277
APA Citation style: Ghosh, B., Hausmann, H., Serafin, M., Lentz, D., & Schlecht, S. (2013). A Comparative Study of the Solution Behavior of Iodotrimethylplatinum(IV) Complexes of Pyridines. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 639(12-13), 2202-2208. https://doi.org/10.1002/zaac.201300277
Keywords
1,2-METALLOTROPIC SHIFTS; C-C; HALIDE-COMPLEXES; H BOND ACTIVATION; Iodotrimethylplatinum(IV); PLATINUM(IV) COMPLEXES; PT(IV); REDUCTIVE ELIMINATION-REACTIONS; Solution behavior; Substituted pyridines; TRIMETHYLPLATINUM(IV) COMPLEXES
