Journalartikel

Synthesis of η2-allene complexes by the reaction of a η1-vinylidene tungsten complex with diazoalkanes


AutorenlisteIpaktschi, J; Rooshenas, P; Dülmer, A

Jahr der Veröffentlichung2006

Seiten1456-1459

ZeitschriftEuropean Journal of Inorganic Chemistry

Heftnummer7

ISSN1434-1948

eISSN1099-0682

DOI Linkhttps://doi.org/10.1002/ejic.200500958

VerlagWiley-VCH Verlag


Abstract
The reaction of the eta(1)-vinylidene complex Cp(CO)(NO)W=C=CH2 (5) with diazomethane, to give complex 8, as well as with ethyl diazoacetate, to give complexes 10 and 11, is described. The crystal structures of these complexes are reported. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)



Zitierstile

Harvard-ZitierstilIpaktschi, J., Rooshenas, P. and Dülmer, A. (2006) Synthesis of η2-allene complexes by the reaction of a η1-vinylidene tungsten complex with diazoalkanes, European Journal of Inorganic Chemistry(7), pp. 1456-1459. https://doi.org/10.1002/ejic.200500958

APA-ZitierstilIpaktschi, J., Rooshenas, P., & Dülmer, A. (2006). Synthesis of η2-allene complexes by the reaction of a η1-vinylidene tungsten complex with diazoalkanes. European Journal of Inorganic Chemistry(7), 1456-1459. https://doi.org/10.1002/ejic.200500958



Schlagwörter


ACETYLIDEALKENYLallene ligandsdiazoalkanesELECTROPHILETRANSITION-METAL-COMPLEXESVINYLIDENE COMPLEXESvinylidene ligands

Zuletzt aktualisiert 2025-02-04 um 03:53