Synthesis of η<SUP>2</SUP>-allene complexes by the reaction of a η<SUP>1</SUP>-vinylidene tungsten complex with diazoalkanes - Research portal of Justus Liebig University Giessen:

Journal article

Synthesis of η²-allene complexes by the reaction of a η¹-vinylidene tungsten complex with diazoalkanes

Authors list: Ipaktschi, J; Rooshenas, P; Dülmer, A

Publication year: 2006

Pages: 1456-1459

Journal: European Journal of Inorganic Chemistry

Issue number: 7

ISSN: 1434-1948

eISSN: 1099-0682

DOI Link: https://doi.org/10.1002/ejic.200500958

Publisher: Wiley-VCH Verlag

Abstract:
The reaction of the eta(1)-vinylidene complex Cp(CO)(NO)W=C=CH2 (5) with diazomethane, to give complex 8, as well as with ethyl diazoacetate, to give complexes 10 and 11, is described. The crystal structures of these complexes are reported. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

Citation Styles

Harvard Citation style: Ipaktschi, J., Rooshenas, P. and Dülmer, A. (2006) Synthesis of η²-allene complexes by the reaction of a η¹-vinylidene tungsten complex with diazoalkanes, European Journal of Inorganic Chemistry(7), pp. 1456-1459. https://doi.org/10.1002/ejic.200500958

APA Citation style: Ipaktschi, J., Rooshenas, P., & Dülmer, A. (2006). Synthesis of η²-allene complexes by the reaction of a η¹-vinylidene tungsten complex with diazoalkanes. European Journal of Inorganic Chemistry(7), 1456-1459. https://doi.org/10.1002/ejic.200500958

Keywords

ACETYLIDE; ALKENYL; allene ligands; diazoalkanes; ELECTROPHILE; TRANSITION-METAL-COMPLEXES; VINYLIDENE COMPLEXES; vinylidene ligands

SDG Areas

12 Responsible consumption and production