Konferenzpaper
Autorenliste: Maier, G; Lautz, C; Reisenauer, HP
Jahr der Veröffentlichung: 2000
Seiten: 25-38
Bandnummer: 25
Heftnummer: 1-2
ISSN: 1025-6008
Konferenz: 16th Conference of the Photochemistry Section of the Society-of-German-Chemists (GDCh)
Abstract:
Upon photolysis in a bromine-doped xenon matrix with lambda = 254 nm propane (3) can be fragmented despite the fact that 3 does not absorb light of this wavelength. A mechanistic model is developed, which can explain this type of indirect photoexcitation. In addition, the behavior of propane (3) in a pure xenon matrix on irradiation with a laser and a mercury lamp is repel-red. The saturated hydrocarbon 3 is not photostable under these experimental conditions, and the corresponding mechanisms leading to its fragmentation are discussed.
Zitierstile
Harvard-Zitierstil: Maier, G., Lautz, C. and Reisenauer, H. (2000) Photoexcitations in halogen-doped and undoped xenon matrices, 16th Conference of the Photochemistry Section of the Society-of-German-Chemists (GDCh), MUNICH, GERMANY. pp. 25-38
APA-Zitierstil: Maier, G., Lautz, C., & Reisenauer, H. (2000). Photoexcitations in halogen-doped and undoped xenon matrices. 16th Conference of the Photochemistry Section of the Society-of-German-Chemists (GDCh), MUNICH, GERMANY.
Schlagwörter
EXCITONS; halogens; IR SPECTROSCOPY; METHYLENECYCLOPROPANE; PHOTODYNAMICS; SOLID XENON; TRIMETHYLENEMETHANE; two-photon process; XE; XENON