Konferenzpaper

Photoexcitations in halogen-doped and undoped xenon matrices


AutorenlisteMaier, G; Lautz, C; Reisenauer, HP

Jahr der Veröffentlichung2000

Seiten25-38

Bandnummer25

Heftnummer1-2

ISSN1025-6008

Konferenz16th Conference of the Photochemistry Section of the Society-of-German-Chemists (GDCh)


Abstract
Upon photolysis in a bromine-doped xenon matrix with lambda = 254 nm propane (3) can be fragmented despite the fact that 3 does not absorb light of this wavelength. A mechanistic model is developed, which can explain this type of indirect photoexcitation. In addition, the behavior of propane (3) in a pure xenon matrix on irradiation with a laser and a mercury lamp is repel-red. The saturated hydrocarbon 3 is not photostable under these experimental conditions, and the corresponding mechanisms leading to its fragmentation are discussed.



Zitierstile

Harvard-ZitierstilMaier, G., Lautz, C. and Reisenauer, H. (2000) Photoexcitations in halogen-doped and undoped xenon matrices, 16th Conference of the Photochemistry Section of the Society-of-German-Chemists (GDCh), MUNICH, GERMANY. pp. 25-38

APA-ZitierstilMaier, G., Lautz, C., & Reisenauer, H. (2000). Photoexcitations in halogen-doped and undoped xenon matrices. 16th Conference of the Photochemistry Section of the Society-of-German-Chemists (GDCh), MUNICH, GERMANY.



Schlagwörter


EXCITONShalogensIR SPECTROSCOPYMETHYLENECYCLOPROPANEPHOTODYNAMICSSOLID XENONTRIMETHYLENEMETHANEtwo-photon processXEXENON


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