Journal article

Small rings .91. Fragmentation of cyclobutane in a bromine-doped and undoped xenon matrix


Authors list: Maier, G; Senger, S

Publication year: 1996

Pages: 45-47

Journal: Liebigs Annalen - recueil

Issue number: 1

ISSN: 0947-3440

Publisher: Wiley-VCH Verlag


Abstract: 
Irradiation (lambda = 254 nm) of cyclobutane in a bromine-doped xenon matrix leads to ring opening in spite of the fact that cyclobutane does not absorb in this region. The main products are ethene and 1-butene. The same reaction, but less effectively, occurs upon irradiation with a laser (KrF laser, lambda = 248 nm) in the absence of the halogen. The difference in the mechanisms of the two fragmentations is discussed.



Citation Styles

Harvard Citation style: Maier, G. and Senger, S. (1996) Small rings .91. Fragmentation of cyclobutane in a bromine-doped and undoped xenon matrix, Liebigs Annalen - recueil(1), pp. 45-47

APA Citation style: Maier, G., & Senger, S. (1996). Small rings .91. Fragmentation of cyclobutane in a bromine-doped and undoped xenon matrix. Liebigs Annalen - recueil(1), 45-47.



Keywords

CHARGE-TRANSFER STATES; exciplexes; EXCITONS; matrix spectroscopy; PHOTODYNAMICS; PHOTOLYSIS; ring opening; SOLID XENON; XE

Last updated on 2025-02-04 at 04:43