Journalartikel

Jahr der Veröffentlichung: 1994

Seiten: 1346-1350

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 620

Heftnummer: 8

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19946200803

Verlag: Wiley

Abstract: 
By oxidizing NaPb with Na2O2 (molar ratio Na2O2: NaPb = 2.04: 1; Ag-tubes; 600-degrees-C/50 d) we obtained for the first time small orange coloured single crystals of Na4[PbO4]: Na4[SiO4]-type [21, P-1 (I.T. No. 2) with a = 898.5(3); b = 675.6(3); c = 592.2(2) pm; alpha = 124.75(1)degrees; beta = 96.75(1)degrees; gamma = 100.18(2)degrees; Z = 2; (four circle diffractometer data (MoKalphaBAR; 3251 I(o)(hkl); R = 3.4%; R(w) = 3.0%), parameters see text. Furthermore the Madelung part of lattice energy (MAPLE), effective coordination numbers (ECoN), mean fictive ionic radii (MEFIR) and the charge distribution (CHARDI) are being calculated.

Harvard-Zitierstil: BRANDES, R. and HOPPE, R. (1994) NA4[PBO4] - PREPARATION OF NEW PLUMBATES(IV) BY OXIDIZING INTERMETALLIC PHASES, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 620(8), pp. 1346-1350. https://doi.org/10.1002/zaac.19946200803

APA-Zitierstil: BRANDES, R., & HOPPE, R. (1994). NA4[PBO4] - PREPARATION OF NEW PLUMBATES(IV) BY OXIDIZING INTERMETALLIC PHASES. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 620(8), 1346-1350. https://doi.org/10.1002/zaac.19946200803