Journal article

Publication year: 1994

Pages: 1346-1350

Journal: Journal of Inorganic and General Chemistry

Volume number: 620

Issue number: 8

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19946200803

Publisher: Wiley

Abstract: 
By oxidizing NaPb with Na2O2 (molar ratio Na2O2: NaPb = 2.04: 1; Ag-tubes; 600-degrees-C/50 d) we obtained for the first time small orange coloured single crystals of Na4[PbO4]: Na4[SiO4]-type [21, P-1 (I.T. No. 2) with a = 898.5(3); b = 675.6(3); c = 592.2(2) pm; alpha = 124.75(1)degrees; beta = 96.75(1)degrees; gamma = 100.18(2)degrees; Z = 2; (four circle diffractometer data (MoKalphaBAR; 3251 I(o)(hkl); R = 3.4%; R(w) = 3.0%), parameters see text. Furthermore the Madelung part of lattice energy (MAPLE), effective coordination numbers (ECoN), mean fictive ionic radii (MEFIR) and the charge distribution (CHARDI) are being calculated.

Harvard Citation style: BRANDES, R. and HOPPE, R. (1994) NA4[PBO4] - PREPARATION OF NEW PLUMBATES(IV) BY OXIDIZING INTERMETALLIC PHASES, Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 620(8), pp. 1346-1350. https://doi.org/10.1002/zaac.19946200803

APA Citation style: BRANDES, R., & HOPPE, R. (1994). NA4[PBO4] - PREPARATION OF NEW PLUMBATES(IV) BY OXIDIZING INTERMETALLIC PHASES. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 620(8), 1346-1350. https://doi.org/10.1002/zaac.19946200803