Journalartikel

Jahr der Veröffentlichung: 1991

Seiten: 41-46

Zeitschrift: Journal of Inorganic and General Chemistry

Bandnummer: 601

Heftnummer: 10

ISSN: 0044-2313

DOI Link: https://doi.org/10.1002/zaac.19916010105

Verlag: Wiley

Abstract: 

By evaporating an aqueous extract of a KOH melt with RuO2 (KOH:RuO2 = 20:1; at air, corundum crucible, 30 min.) rubin-red single crystals of K2[RuO3(OH)2] have been prepared. Up to this day pure samples could not be prepared.

The structure determination (four circle diffractometer, MoK-alpha-BAR, 1 664 I(o) (hkl), R = 2,1%) confirms a new type of structure [space group P2(1)2(1)2(1) (Nr. 19) with a = 803.1(5), b = 669.9(3) and c = 1 061.6(6) pm]. Ru is trigonal-bipyramidale coordinated.

Harvard-Zitierstil: FISCHER, D. and HOPPE, R. (1991) ON THE CONSTITUTION OF RUTHENATES(VI) WITH ALKALI-METALS .2. ON THE STRUCTURE OF K2[RUO3(OH)2], Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry, 601(10), pp. 41-46. https://doi.org/10.1002/zaac.19916010105

APA-Zitierstil: FISCHER, D., & HOPPE, R. (1991). ON THE CONSTITUTION OF RUTHENATES(VI) WITH ALKALI-METALS .2. ON THE STRUCTURE OF K2[RUO3(OH)2]. Zeitschrift für anorganische und allgemeine Chemie = Journal of Inorganic and General Chemistry. 601(10), 41-46. https://doi.org/10.1002/zaac.19916010105