Journalartikel
Autorenliste: Zhu, C; Bergantini, A; Singh, SK; Kaiser, RI; Eckhardt, AK; Schreiner, PR; Huang, YS; Sun, BJ; Chang, AHH
Jahr der Veröffentlichung: 2021
Seiten: 4958-4961
Zeitschrift: Chemical Communications
Bandnummer: 57
Heftnummer: 40
ISSN: 1359-7345
DOI Link: https://doi.org/10.1039/d0cc08411e
Verlag: Royal Society of Chemistry
Abstract:
We present the first formation of the previously elusive phosphine imide (HN PH3) along with its phosphinous amide (H2N-PH2) isomer via exposure of phosphine (PH3) and ammonia (NH3) ices to ionizing radiation. Our approach may be extended to prepare, separate, and detect highly reactive compounds such as intermediates of Wittig reactions.
Zitierstile
Harvard-Zitierstil: Zhu, C., Bergantini, A., Singh, S., Kaiser, R., Eckhardt, A., Schreiner, P., et al. (2021) Formation of phosphine imide (HN=PH3) and its phosphinous amide (H2N-PH2) isomer, Chemical Communications, 57(40), pp. 4958-4961. https://doi.org/10.1039/d0cc08411e
APA-Zitierstil: Zhu, C., Bergantini, A., Singh, S., Kaiser, R., Eckhardt, A., Schreiner, P., Huang, Y., Sun, B., & Chang, A. (2021). Formation of phosphine imide (HN=PH3) and its phosphinous amide (H2N-PH2) isomer. Chemical Communications. 57(40), 4958-4961. https://doi.org/10.1039/d0cc08411e
