Journal article
Authors list: Zhu, C; Bergantini, A; Singh, SK; Kaiser, RI; Eckhardt, AK; Schreiner, PR; Huang, YS; Sun, BJ; Chang, AHH
Publication year: 2021
Pages: 4958-4961
Journal: Chemical Communications
Volume number: 57
Issue number: 40
ISSN: 1359-7345
DOI Link: https://doi.org/10.1039/d0cc08411e
Publisher: Royal Society of Chemistry
Abstract:
We present the first formation of the previously elusive phosphine imide (HN PH3) along with its phosphinous amide (H2N-PH2) isomer via exposure of phosphine (PH3) and ammonia (NH3) ices to ionizing radiation. Our approach may be extended to prepare, separate, and detect highly reactive compounds such as intermediates of Wittig reactions.
Citation Styles
Harvard Citation style: Zhu, C., Bergantini, A., Singh, S., Kaiser, R., Eckhardt, A., Schreiner, P., et al. (2021) Formation of phosphine imide (HN=PH3) and its phosphinous amide (H2N-PH2) isomer, Chemical Communications, 57(40), pp. 4958-4961. https://doi.org/10.1039/d0cc08411e
APA Citation style: Zhu, C., Bergantini, A., Singh, S., Kaiser, R., Eckhardt, A., Schreiner, P., Huang, Y., Sun, B., & Chang, A. (2021). Formation of phosphine imide (HN=PH3) and its phosphinous amide (H2N-PH2) isomer. Chemical Communications. 57(40), 4958-4961. https://doi.org/10.1039/d0cc08411e
